Information card for entry 7061677

Structure parameters

• Formula: C30 H66 O7 P2 Rh2 Si2
• Calculated formula: C30 H66 O7 P2 Rh2 Si2
• SMILES: [Rh]12345([Rh]6([P](C)(C)C)([P](C)(C)C)[O]1[Si](O[Si]([O]26)(OC(C)(C)C)OC(C)(C)C)(OC(C)(C)C)OC(C)(C)C)[CH]1=[CH]4CC[CH]5=[CH]3CC1
• Title of publication: Multinuclear rhodium complexes supported by tetra-tert-butoxy disiloxide ligand: synthesis, structure, and reactivity
• Authors of publication: Ishizaka, Yusuke; Matsumoto, Kazuhiro; Sato, Kazuhiko; Choi, Jun-Chul
• Journal of publication: New Journal of Chemistry
• Year of publication: 2022
• Journal volume: 46
• Journal issue: 33
• Pages of publication: 16040 - 16046
• a: 20.3842 ± 0.0004 Å
• b: 11.6384 ± 0.0002 Å
• c: 17.9317 ± 0.0004 Å
• α: 90°
• β: 108.738 ± 0.002°
• γ: 90°
• Cell volume: 4028.63 ± 0.15 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0296
• Residual factor for significantly intense reflections: 0.0251
• Weighted residual factors for significantly intense reflections: 0.1032
• Weighted residual factors for all reflections included in the refinement: 0.1081
• Goodness-of-fit parameter for all reflections included in the refinement: 0.924
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No