Information card for entry 7100010

Structure parameters

• Formula: C21 H43 Cl2 P Ru Si
• Calculated formula: C21 H43 Cl2 P Ru Si
• SMILES: [RuH]1234(Cl)([P](C(C)C)(C(C)C)C(C)C)([Si](Cl)(C)C)[c]5([c]1([c]2([c]3([c]45C)C)C)C)C
• Title of publication: Cp*(iPr3P)Ru(Cl)(η2-HSiClMe2): the first complex with simultaneous Si‒H and RuCl⋯SiCl inter-ligand interactions
• Authors of publication: Osipov, Alexander L.; Vyboishchikov, Sergei F.; Dorogov, Konstantin Y.; Kuzmina, Lyudmila G.; Howard, Judith A. K.; Lemenovskii, Dmitrii A.; Nikonov, Georgii I.
• Journal of publication: Chemical Communications (Cambridge, United Kingdom)
• Year of publication: 2005
• Journal issue: 26
• Pages of publication: 3349 - 3351
• a: 10.9544 ± 0.0003 Å
• b: 15.0911 ± 0.0004 Å
• c: 15.4986 ± 0.0004 Å
• α: 90°
• β: 99.898 ± 0.001°
• γ: 90°
• Cell volume: 2524 ± 0.12 ų
• Cell temperature: 123 ± 2 K
• Ambient diffraction temperature: 123 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No