Information card for entry 7100082

Structure parameters

• Formula: C48 H55 B F20 N6 Si Ti
• Calculated formula: C48 H55 B F20 N6 Si Ti
• Title of publication: Well-defined imidotitanium alkyl cations: alpha-C-H or beta-Si-C agostic interactions, migratory insertion vs [2+2] cycloaddition, and the first structurally authenticated AlMe3 adduct of any transition metal alkyl cation
• Authors of publication: Philip Mountford; Paul D. Bolton; Eric Clot; Andrew R. Cowley
• Journal of publication: Chemical Communications
• Year of publication: 2005
• a: 11.9619 ± 0.0002 Å
• b: 12.7619 ± 0.0002 Å
• c: 17.984 ± 0.0002 Å
• α: 75.5723 ± 0.0005°
• β: 80.1952 ± 0.0005°
• γ: 86.9238 ± 0.0005°
• Cell volume: 2619.78 ± 0.07 ų
• Cell temperature: 150 K
• Ambient diffraction temperature: 150 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No