Information card for entry 7100305

Structure parameters

• Formula: C94 H106 I2 O4 P4 S4 Sm2
• Calculated formula: C94 H106 I2 O4 P4 S4 Sm2
• SMILES: C12[Sm]3([O]4CCCC4)([I][Sm]45([O]6CCCC6)([I]3)([O]3CCCC3)[S]=P(C5=P(S4)(c3ccccc3)c3ccccc3)(c3ccccc3)c3ccccc3)([O]3CCCC3)([S]=P1(c1ccccc1)c1ccccc1)SP=2(c1ccccc1)c1ccccc1.Cc1ccccc1.Cc1ccccc1.Cc1ccccc1.Cc1ccccc1
• Title of publication: New mono and bis-carbene samarium complexes: Synthesis, X-Ray structure and reactivity.
• Authors of publication: T.Cantat; F.Jaroschik; N.Mezailles; F.Nief; L.Ricard; P. Le Floch
• Journal of publication: Chemical Communications
• Year of publication: 2005
• a: 23.338 ± 0.001 Å
• b: 27.19 ± 0.001 Å
• c: 18.109 ± 0.001 Å
• α: 90°
• β: 128.174 ± 0.001°
• γ: 90°
• Cell volume: 9033.7 ± 0.7 ų
• Cell temperature: 150 ± 0.1 K
• Ambient diffraction temperature: 150 ± 0.1 K
• Number of distinct elements: 7
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No