Information card for entry 7100395

Structure parameters

• Common name: (Pt2(mu–kappaP:eta2- P(tBu)2–CC–Ph)(mu,eta2–C(Ph)CH2)(CO)(P(tBu)2H))(PF6)
• Formula: C37 H59 F6 O3 P3 Pt2
• Calculated formula: C37 H59 F6 O3 P3 Pt2
• SMILES: [Pt]123(C([P]([Pt]41(C#[O])[CH2]=[C]24c1ccccc1)(C(C)(C)C)C(C)(C)C)=C3c1ccccc1)[PH](C(C)(C)C)C(C)(C)C.[P](F)(F)(F)(F)(F)[F-].O(C)CCOC
• Title of publication: Unprecedented Reversible Coupling of Alkynyl and Phosphide ligands on a Dinuclear Platinum Framework
• Authors of publication: A. Albinati; Valeria Filippi; Piero Leoni; Lorella Marchetti; Marco Pasquali; V. Passarelli
• Journal of publication: Chemical Communications
• Year of publication: 2005
• a: 16.7547 ± 0.0001 Å
• b: 20.0887 ± 0.0001 Å
• c: 25.9733 ± 0.0003 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 8742.1 ± 0.1 ų
• Cell temperature: 200 ± 2 K
• Ambient diffraction temperature: 200 ± 2 K
• Number of distinct elements: 6
• Space group number: 61
• Hermann-Mauguin space group symbol: P b c a
• Hall space group symbol: -P 2ac 2ab
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No