Information card for entry 7100587

Structure parameters

• Formula: C32 H41 Al Cl6 N3 O2 P W
• Calculated formula: C32 H41 Al Cl6 N3 O2 P W
• SMILES: [W]123456(P(N2[N]1=C(c1ccccc1)c1ccccc1)N(C(C)C)C(C)C)(C#[O])(C#[O])[c]1([c]3([c]4([c]5([c]61C)C)C)C)C.Cl[Al](Cl)(Cl)Cl.ClCCl
• Title of publication: Reactivity Patterns of Thermally Stable, Terminal, Electrophilic Phosphinidene Complexes Towards Diazoalkanes: Oxidation at the Phosphorus Centre and Formation of P-bound h1-Phosphaimine, h1-Phosphaalkene and h3-Diazaphosphaallene Complexes.
• Authors of publication: A. Carty; Todd Graham; Konstantin A. Udachin
• Journal of publication: Chemical Communications
• Year of publication: 2005
• a: 11.615 ± 0.003 Å
• b: 14.159 ± 0.004 Å
• c: 24.833 ± 0.006 Å
• α: 90°
• β: 105.265 ± 0.011°
• γ: 90°
• Cell volume: 3939.9 ± 1.8 ų
• Cell temperature: 125 ± 2 K
• Ambient diffraction temperature: 125 ± 2 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No