Information card for entry 7100659

Structure parameters

• Formula: C35 H49 N O2 Si2 W
• Calculated formula: C35 H48 N O2 Si2 W
• SMILES: [W]123456([Si](C)(C)c7cccc8c7Oc7c([Si]([N]1=C2C(C)(C)C)(C)C)cccc7C8(C)C)(C#[O])[c]1([c]6([c]5([c]4([c]31C)C)C)C)C
• Title of publication: Group 6 metal xantsil complexes with a labile oxygen coordination and insertion of tBuCN into a W-Si bond [xantsil = (9,9-dimethylxantene- 4,5-diyl)bis(dimethylsilyl)]
• Authors of publication: Rockshana Begum; Takashi Komuro; Hiromi Tobita
• Journal of publication: Chemical Communications
• Year of publication: 2006
• a: 11.3139 ± 0.0005 Å
• b: 14.837 ± 0.0005 Å
• c: 20.5961 ± 0.0007 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 3457.4 ± 0.2 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 6
• Space group number: 19
• Hermann-Mauguin space group symbol: P 21 21 21
• Hall space group symbol: P 2ac 2ab
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No