Information card for entry 7101502

Structure parameters

• Formula: C32 H76 Au Cl5 Ni0 O6 P8 Pt6
• Calculated formula: C32 H76 Au Cl5 O6 P8 Pt6
• SMILES: C[P](C)(C)[Pt]1234[Au]567([Pt]82([P](C)(C)C)([P](C)(C)C)(C1=O)C(=O)[Pt]458([P](C)(C)C)C3=O)[Pt]123([P](C)(C)C)C(=O)[Pt]473([P](C)(C)C)([P](C)(C)C)C(=O)[Pt]624([P](C)(C)C)C1=O.[Cl-].ClCCl.ClCCl
• Title of publication: Structural/bonding insights from new geometrical varieties of two Pt-Au carbonyl/phosphine clusters, [Pt3(AuPPh3)5(?2-CO)2L3]+ (L3 = (CO)2PPh3) and [(?6-Au){Pt3(?2-CO)3L4} 2]+ (L = PMe3)
• Authors of publication: Lawrence Dahl; N.de Silva; Jeffrey W. Laufenberg
• Journal of publication: Chemical Communications
• Year of publication: 2006
• Journal issue: 42
• a: 11.4443 ± 0.0011 Å
• b: 11.728 ± 0.0012 Å
• c: 13.1419 ± 0.0013 Å
• α: 68.521 ± 0.002°
• β: 73.391 ± 0.002°
• γ: 64.811 ± 0.001°
• Cell volume: 1467.5 ± 0.3 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 8
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0372
• Residual factor for significantly intense reflections: 0.0339
• Weighted residual factors for significantly intense reflections: 0.0888
• Weighted residual factors for all reflections included in the refinement: 0.0944
• Goodness-of-fit parameter for all reflections included in the refinement: 1.079
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No