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Information card for entry 7102773
Preview
Coordinates | 7102773.cif |
---|---|
Original paper (by DOI) | HTML |
Formula | C24 H39 I6 O Si3 U3 |
---|---|
Calculated formula | C24 H39 I6 O Si3 U3 |
SMILES | [U]12345678([I][U]9%10%11%12%13%14([I]1)([I][U]1%15%16%17([I]9)([I]2)([I]3)([O]4%10)[c]2([cH]%17[cH]%16[cH]%15[cH]12)[Si](C)(C)C)[c]1([Si](C)(C)C)[cH]%11[cH]%12[cH]%13[cH]%141)[c]1([Si](C)(C)C)[cH]5[cH]6[cH]7[cH]81 |
Title of publication | Activation and reduction of diethyl ether by low valent uranium: formation of the trimetallic, mixed valence uranium oxo species [U(CpRR')(μ-I)2]3(μ3-O) (CpRR' = C5Me5, C5Me4H, C5H4SiMe3) |
Authors of publication | Larch, Christopher P.; Cloke, F. Geoffrey N.; Hitchcock, Peter B. |
Journal of publication | Chemical Communications (Cambridge, United Kingdom) |
Year of publication | 2008 |
Journal issue | 1 |
Pages of publication | 82 - 84 |
a | 16.707 ± 0.0003 Å |
b | 8.3748 ± 0.0001 Å |
c | 31.3762 ± 0.0004 Å |
α | 90° |
β | 102.745 ± 0.001° |
γ | 90° |
Cell volume | 4281.92 ± 0.11 Å3 |
Cell temperature | 173 ± 2 K |
Ambient diffraction temperature | 173 ± 2 K |
Number of distinct elements | 6 |
Space group number | 14 |
Hermann-Mauguin space group symbol | P 1 21/c 1 |
Hall space group symbol | -P 2ybc |
Residual factor for all reflections | 0.0592 |
Residual factor for significantly intense reflections | 0.0451 |
Weighted residual factors for significantly intense reflections | 0.11 |
Weighted residual factors for all reflections included in the refinement | 0.1182 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.03 |
Diffraction radiation probe | x-ray |
Diffraction radiation wavelength | 0.71073 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | Yes |
Has Fobs | No |
For the version history of this entry, please navigate to main COD server.
The link is: https://www.crystallography.net/7102773.html
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Users of the data should acknowledge the original authors of the
structural data.