Information card for entry 7103083

Structure parameters

• Common name: ?=20
• Formula: C14 H21 N O3 Si
• Calculated formula: C14 H21 N O3 Si
• SMILES: [Si](C(=C)[C@@H]([C@@H](O)c1ccc(N(=O)=O)cc1)C)(C)(C)C.[Si](C(=C)[C@H]([C@H](O)c1ccc(N(=O)=O)cc1)C)(C)(C)C
• Title of publication: Preparation of silyl substituted crotylzinc reagents and their highly diastereoselective addition to carbonyl compounds.
• Authors of publication: Helm, Matthew D; Mayer, Peter; Knochel, Paul
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2008
• Journal issue: 16
• Pages of publication: 1916 - 1917
• a: 7.1579 ± 0.0002 Å
• b: 8.0414 ± 0.0002 Å
• c: 15.3538 ± 0.0003 Å
• α: 98.8045 ± 0.0014°
• β: 96.7877 ± 0.0014°
• γ: 112.581 ± 0.0014°
• Cell volume: 791.08 ± 0.03 ų
• Cell temperature: 200 ± 2 K
• Ambient diffraction temperature: 200 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0439
• Residual factor for significantly intense reflections: 0.038
• Weighted residual factors for significantly intense reflections: 0.099
• Weighted residual factors for all reflections included in the refinement: 0.1033
• Goodness-of-fit parameter for all reflections included in the refinement: 1.046
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No