Information card for entry 7103282

Structure parameters

• Formula: C25 H51 Co N2 O3 P2 Si
• Calculated formula: C25 H51 Co N2 O3 P2 Si
• SMILES: [Co]12([P](CC[N]1([Si](N(C(C)(C)C)C2=O)(C)C)CCP(C(C)C)C(C)C)(C(C)C)C(C)C)(C#[O])C#[O]
• Title of publication: Reactivity of a Co(i) [N(2)P(2)] complex with azides: evidence for a transient Co(iii) imido species.
• Authors of publication: Chomitz, Wayne A; Arnold, John
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2008
• Journal issue: 31
• Pages of publication: 3648 - 3650
• a: 8.3023 ± 0.0011 Å
• b: 12.2795 ± 0.0017 Å
• c: 15.354 ± 0.002 Å
• α: 90°
• β: 93.718 ± 0.002°
• γ: 90°
• Cell volume: 1562.1 ± 0.4 ų
• Cell temperature: 160 ± 2 K
• Ambient diffraction temperature: 160 ± 2 K
• Number of distinct elements: 7
• Space group number: 4
• Hermann-Mauguin space group symbol: P 1 21 1
• Hall space group symbol: P 2yb
• Residual factor for all reflections: 0.0535
• Residual factor for significantly intense reflections: 0.0417
• Weighted residual factors for significantly intense reflections: 0.0889
• Weighted residual factors for all reflections included in the refinement: 0.093
• Goodness-of-fit parameter for all reflections included in the refinement: 0.936
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No