Information card for entry 7103635

Structure parameters

• Formula: C58 H64 Ag2 F6 Ir2 O6 P2 S2
• Calculated formula: C58 H60 Ag2 F6 Ir2 O6 P2 S2
• SMILES: [c]12([c]3([c]4([c]5([c]1(C)[Ir]12345([P](c2ccccc2)(c2ccccc2)c2ccccc2)[Ag]2([Ag]1(OS(=O)(=O)C(F)(F)F)[Ir]13452([c]2([c]1([c]3([c]4([c]52C)C)C)C)C)[P](c1ccccc1)(c1ccccc1)c1ccccc1)OS(=O)(=O)C(F)(F)F)C)C)C)C
• Title of publication: Unprecedented stabilisation of the Ag~2~^2+^-ion by two hydrido-iridium(III) complexes
• Authors of publication: Gorol, Michael; Mösch-Zanetti, Nadia C.; Roesky, Herbert W.; Noltemeyer, Mathias; Schmidt, Hans-Georg
• Journal of publication: Chemical Communications (Cambridge, United Kingdom)
• Year of publication: 2003
• Journal issue: 1
• Pages of publication: 46 - 47
• a: 10.13 ± 0.002 Å
• b: 11.186 ± 0.003 Å
• c: 14.477 ± 0.004 Å
• α: 71.179 ± 0.019°
• β: 72.004 ± 0.011°
• γ: 89.714 ± 0.011°
• Cell volume: 1468.6 ± 0.7 ų
• Cell temperature: 200 ± 2 K
• Ambient diffraction temperature: 200 ± 2 K
• Number of distinct elements: 8
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0438
• Residual factor for significantly intense reflections: 0.0404
• Weighted residual factors for significantly intense reflections: 0.1041
• Weighted residual factors for all reflections included in the refinement: 0.1074
• Goodness-of-fit parameter for all reflections included in the refinement: 1.054
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No