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Information card for entry 7103968
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Coordinates | 7103968.cif |
---|---|
Original paper (by DOI) | HTML |
Common name | (CGC)phosphium arsenium tetrachloride |
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Chemical name | t-butyl(dimetyl(tetra-methylcyclopentadienyl)silyl)amido arsenium aluminum tetrachloride |
Formula | C15 H27 Al As Cl4 N Si |
Calculated formula | C15 H27 Al As Cl4 N Si |
SMILES | C12(C(=C(C(=C1[As]=[N+](C(C)(C)C)[Si]2(C)C)C)C)C)C.[Al](Cl)(Cl)(Cl)[Cl-] |
Title of publication | The contrasting behaviour of bridged amido-cyclopentadienyl (constrained geometry) group 15 chlorides and cations derived therefrom |
Authors of publication | Wiacek, Robert J.; Macdonald, Charles L. B.; Jones, Jamie N.; Pietryga, Jeffrey M.; Cowley, Alan H. |
Journal of publication | Chemical Communications (Cambridge, United Kingdom) |
Year of publication | 2003 |
Journal issue | 3 |
Pages of publication | 430 - 431 |
a | 18.184 ± 0.004 Å |
b | 8.2774 ± 0.0017 Å |
c | 30.284 ± 0.006 Å |
α | 90° |
β | 90° |
γ | 90° |
Cell volume | 4558.2 ± 1.6 Å3 |
Cell temperature | 153 ± 2 K |
Ambient diffraction temperature | 153 ± 2 K |
Number of distinct elements | 7 |
Space group number | 29 |
Hermann-Mauguin space group symbol | P c a 21 |
Hall space group symbol | P 2c -2ac |
Residual factor for all reflections | 0.0918 |
Residual factor for significantly intense reflections | 0.0678 |
Weighted residual factors for significantly intense reflections | 0.1544 |
Weighted residual factors for all reflections included in the refinement | 0.172 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.061 |
Diffraction radiation wavelength | 0.71073 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
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