Information card for entry 7103997

Structure parameters

• Formula: C52 H42 Cl4 O2 P2 Pt Ti
• Calculated formula: C52 H42 Cl4 O2 P2 Pt Ti
• Title of publication: A quasi-covalent metal‒metal bond in an early‒late heterobimetallic Ti‒Pt complex stabilized by phosphinoenolate ligands
• Authors of publication: Braunstein, Pierre; Morise, Xavier; Bénard, Marc; Rohmer, Marie-Madeleine; Welter, Richard
• Journal of publication: Chemical Communications (Cambridge, United Kingdom)
• Year of publication: 2003
• Journal issue: 5
• Pages of publication: 610 - 611
• a: 11.963 ± 0.002 Å
• b: 15.433 ± 0.003 Å
• c: 16.42 ± 0.004 Å
• α: 65.104 ± 0.01°
• β: 81.432 ± 0.01°
• γ: 86.044 ± 0.01°
• Cell volume: 2719 ± 1 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0957
• Residual factor for significantly intense reflections: 0.0696
• Weighted residual factors for significantly intense reflections: 0.1844
• Weighted residual factors for all reflections included in the refinement: 0.2009
• Goodness-of-fit parameter for all reflections included in the refinement: 1.029
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No