Information card for entry 7104069

Structure parameters

• Formula: C18 H39 Al2 Lu
• Calculated formula: C18 H39 Al2 Lu
• SMILES: [Lu]12345678([Al]([CH3]5)([CH3]6)(C)C)([Al]([CH3]7)([CH3]8)(C)C)[c]5([c]1([c]2([c]3([c]45C)C)C)C)C
• Title of publication: High tetraalkylaluminate fluxionality in half-sandwich complexes of the trivalent rare-earth metals
• Authors of publication: Anwander, Reiner; Klimpel, Michael G.; Dietrich, H. Martin; Shorokhov, Dmitry J.; Scherer, Wolfgang
• Journal of publication: Chemical Communications (Cambridge, United Kingdom)
• Year of publication: 2003
• Journal issue: 8
• Pages of publication: 1008 - 1009
• a: 17.2295 ± 0.0001 Å
• b: 14.369 ± 0.0001 Å
• c: 17.9638 ± 0.0001 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 4447.31 ± 0.05 ų
• Cell temperature: 173 K
• Ambient diffraction temperature: 173 K
• Number of distinct elements: 4
• Space group number: 61
• Hermann-Mauguin space group symbol: P b c a
• Hall space group symbol: -P 2ac 2ab
• Residual factor for all reflections: 0.0253
• Residual factor for significantly intense reflections: 0.0208
• Weighted residual factors for significantly intense reflections: 0.0478
• Weighted residual factors for all reflections included in the refinement: 0.0499
• Goodness-of-fit parameter for all reflections included in the refinement: 1.137
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No