Information card for entry 7104190

Structure parameters

• Formula: C37 H32 Cl2 Co P2
• Calculated formula: C37 H32 Cl2 Co P2
• SMILES: [Co]([P](c1ccccc1)(c1ccccc1)c1ccccc1)(Cl)(Cl)C[P+](c1ccccc1)(c1ccccc1)c1ccccc1
• Title of publication: Facile dichloromethane activation and phosphine methylation. Isolation of unprecedented zwitterionic organozinc and organocobalt intermediates.
• Authors of publication: Pattacini, Roberto; Jie, Suyun; Braunstein, Pierre
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2009
• Journal volume: 34
• Journal issue: 8
• Pages of publication: 890 - 892
• a: 24.424 ± 0.001 Å
• b: 12.4343 ± 0.0009 Å
• c: 22.853 ± 0.001 Å
• α: 90°
• β: 90.804 ± 0.004°
• γ: 90°
• Cell volume: 6939.7 ± 0.7 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 5
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.1454
• Residual factor for significantly intense reflections: 0.0753
• Weighted residual factors for significantly intense reflections: 0.2064
• Weighted residual factors for all reflections included in the refinement: 0.231
• Goodness-of-fit parameter for all reflections included in the refinement: 1.012
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No