Information card for entry 7104802

Structure parameters

• Common name: (tetra-mu-di-t-butylphosphido)-tetracarbonyl- bisphenylacetylide -hexaplatinum(i)
• Chemical name: (tetra-μ-di-t-butylphosphido)-tetracarbonyl-bisphenylacetylide -hexaplatinum(i)
• Formula: C52 H82 O4 P4 Pt6
• Calculated formula: C52 H82 O4 P4 Pt6
• SMILES: [Pt]1234([Pt]5([Pt]61([Pt]172([Pt]2([Pt]361([P]2(C(C)(C)C)C(C)(C)C)C#[O])([P]7(C(C)(C)C)C(C)(C)C)C#Cc1ccccc1)C#[O])([P]5(C(C)(C)C)C(C)(C)C)C#[O])([P]4(C(C)(C)C)C(C)(C)C)C#Cc1ccccc1)C#[O]
• Title of publication: Trinuclear and hexanuclear platinum clusters as building blocks for organometallic one-dimensional structures
• Authors of publication: Leoni, Piero; Marchetti, Fabio; Marchetti, Lorella; Pasquali, Marco
• Journal of publication: Chemical Communications (Cambridge, United Kingdom)
• Year of publication: 2003
• Journal issue: 18
• Pages of publication: 2372 - 2373
• a: 24.797 ± 0.004 Å
• b: 17.712 ± 0.002 Å
• c: 31.646 ± 0.006 Å
• α: 90°
• β: 112.72 ± 0.02°
• γ: 90°
• Cell volume: 12821 ± 4 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 5
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.1445
• Residual factor for significantly intense reflections: 0.0647
• Weighted residual factors for significantly intense reflections: 0.1211
• Weighted residual factors for all reflections included in the refinement: 0.1493
• Goodness-of-fit parameter for all reflections included in the refinement: 1.037
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No