Information card for entry 7104961

Structure parameters

• Common name: ((P)Au(eta2-H2C=C(CH2)5))+ SbF6-
• Formula: C27 H39 Au F6 P Sb
• Calculated formula: C27 H39 Au F6 P Sb
• SMILES: [Au]1([P](C(C)(C)C)(C(C)(C)C)c2c(cccc2)c2ccccc2)[CH2]=[C]21CCCCC2.[Sb](F)(F)(F)([F-])(F)F
• Title of publication: Syntheses and X-ray crystal structures of cationic, two-coordinate gold(I) pi-alkene complexes that contain a sterically hindered o-biphenylphosphine ligand.
• Authors of publication: Brown, Timothy J; Dickens, Marina G; Widenhoefer, Ross A
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2009
• Journal issue: 42
• Pages of publication: 6451 - 6453
• a: 8.1045 ± 0.0009 Å
• b: 17.2929 ± 0.0019 Å
• c: 20.611 ± 0.002 Å
• α: 90°
• β: 95.833 ± 0.006°
• γ: 90°
• Cell volume: 2873.6 ± 0.6 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0436
• Residual factor for significantly intense reflections: 0.0285
• Weighted residual factors for significantly intense reflections: 0.0612
• Weighted residual factors for all reflections included in the refinement: 0.065
• Goodness-of-fit parameter for all reflections included in the refinement: 1.142
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No