Information card for entry 7105237

Structure parameters

• Common name: (Pt(IMes)2(Me2))
• Formula: C44 H54 N4 Pt
• Calculated formula: C44 H54 N4 Pt
• SMILES: [Pt](=C1N(C=CN1c1c(cc(cc1C)C)C)c1c(cc(cc1C)C)C)(=C1N(C=CN1c1c(cc(cc1C)C)C)c1c(cc(cc1C)C)C)(C)C
• Title of publication: Unusual reactivities of N-heterocyclic carbenes upon coordination to the platinum(II)-dimethyl moiety.
• Authors of publication: Fortman, George C; Scott, Natalie M; Linden, Anthony; Stevens, Edwin D; Dorta, Reto; Nolan, Steven P
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2010
• Journal volume: 46
• Journal issue: 7
• Pages of publication: 1050 - 1052
• a: 16.7156 ± 0.001 Å
• b: 13.1785 ± 0.0008 Å
• c: 17.6422 ± 0.001 Å
• α: 90°
• β: 99.411 ± 0.001°
• γ: 90°
• Cell volume: 3834 ± 0.4 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 4
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.042
• Residual factor for significantly intense reflections: 0.0312
• Weighted residual factors for significantly intense reflections: 0.0588
• Weighted residual factors for all reflections included in the refinement: 0.0627
• Goodness-of-fit parameter for all reflections included in the refinement: 1.231
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No