Information card for entry 7105808

Structure parameters

• Chemical name: N-methyl-3-(dimethylamino-methylidenyl)-4,5-dihydropyrrolyliden-2-yl- bis-(triphenylphosphine)-chloro-platinum(ii) tetrafluoroborate dichloromethane solute
• Formula: C45 H46 B Cl3 F4 N2 P2 Pt
• Calculated formula: C45 H46 B Cl3 F4 N2 P2 Pt
• Title of publication: Metal complexes with carbene ligands stabilized by lateral enamines
• Authors of publication: Manuel Alcarazo; Karin Radkowski; Richard Goddard; Alois Furstner
• Journal of publication: Chem.Commun.
• Year of publication: 2011
• Journal volume: 47
• Pages of publication: 776
• a: 15.591 ± 0.0001 Å
• b: 15.9173 ± 0.0001 Å
• c: 17.8073 ± 0.0002 Å
• α: 90°
• β: 99.45 ± 0.001°
• γ: 90°
• Cell volume: 4359.21 ± 0.06 ų
• Cell temperature: 100 K
• Ambient diffraction temperature: 100 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0367
• Residual factor for significantly intense reflections: 0.0308
• Weighted residual factors for significantly intense reflections: 0.0766
• Weighted residual factors for all reflections included in the refinement: 0.0809
• Goodness-of-fit parameter for all reflections included in the refinement: 1.047
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No