Information card for entry 7107227

Structure parameters

• Formula: C23 H36 Cl N P Rh Si
• Calculated formula: C23 H36 Cl N P Rh Si
• SMILES: [RhH]12([Si](C)(c3c([P]1(C(C)(C)C)C(C)(C)C)cccc3)c1c([N]2(C)C)cccc1)Cl
• Title of publication: 'Hemilabile' silyl pincer ligation: platinum group PSiN complexes and triple C-H activation to form a (PSiC)Ru carbene complex
• Authors of publication: Adam J. Ruddy; Samuel Mitton; Robert McDonald; Laura Turculet
• Journal of publication: Chem.Commun.
• Year of publication: 2012
• Journal volume: 48
• Pages of publication: 1159
• a: 15.862 ± 0.0004 Å
• b: 10.3058 ± 0.0002 Å
• c: 16.0399 ± 0.0004 Å
• α: 90°
• β: 113.081 ± 0.0002°
• γ: 90°
• Cell volume: 2412.16 ± 0.1 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0204
• Residual factor for significantly intense reflections: 0.0197
• Weighted residual factors for significantly intense reflections: 0.0568
• Weighted residual factors for all reflections included in the refinement: 0.0574
• Goodness-of-fit parameter for all reflections included in the refinement: 1.045
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No