Information card for entry 7107981

Structure parameters

• Common name: Ni(N(SiMe3)(DIPP))2(MeCN)
• Formula: C32 H55 N3 Ni Si2
• Calculated formula: C32 H55 N3 Ni Si2
• SMILES: c1(c(cccc1C(C)C)C(C)C)N([Si](C)(C)C)[Ni](N(c1c(cccc1C(C)C)C(C)C)[Si](C)(C)C)[N]#CC
• Title of publication: Synthesis and reactivity of a conveniently prepared two-coordinate bis(amido) nickel(II) complex
• Authors of publication: Michael Lipschutz; T.Don Tilley
• Journal of publication: Chem.Commun.
• Year of publication: 2012
• Journal volume: 48
• Pages of publication: 7146
• a: 9.6047 ± 0.0003 Å
• b: 11.1888 ± 0.0004 Å
• c: 17.6838 ± 0.0005 Å
• α: 97.463 ± 0.001°
• β: 97.333 ± 0.002°
• γ: 110.211 ± 0.002°
• Cell volume: 1737.61 ± 0.1 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0337
• Residual factor for significantly intense reflections: 0.028
• Weighted residual factors for significantly intense reflections: 0.0666
• Weighted residual factors for all reflections included in the refinement: 0.0694
• Goodness-of-fit parameter for all reflections included in the refinement: 1.034
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No