Information card for entry 7109043

Structure parameters

• Formula: C36 H72 Co N4
• Calculated formula: C36 H72 Co N4
• SMILES: [Co](N=C(C(C)(C)C)C(C)(C)C)(N=C(C(C)(C)C)C(C)(C)C)(N=C(C(C)(C)C)C(C)(C)C)N=C(C(C)(C)C)C(C)(C)C
• Title of publication: Synthesis of a cobalt(IV) ketimide with a squashed tetrahedral geometry
• Authors of publication: Richard A. Lewis; Stephen P. George; Alon Chapovetsky; Guang Wu; Joshua S. Figueroa; Trevor W. Hayton
• Journal of publication: Chem.Commun.
• Year of publication: 2013
• Journal volume: 49
• Pages of publication: 2888
• a: 11.3082 ± 0.0009 Å
• b: 11.5753 ± 0.001 Å
• c: 16.4021 ± 0.0014 Å
• α: 70.22 ± 0.003°
• β: 78.481 ± 0.003°
• γ: 73.509 ± 0.003°
• Cell volume: 1924.4 ± 0.3 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 4
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0963
• Residual factor for significantly intense reflections: 0.061
• Weighted residual factors for significantly intense reflections: 0.1619
• Weighted residual factors for all reflections included in the refinement: 0.1755
• Goodness-of-fit parameter for all reflections included in the refinement: 0.977
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No