Information card for entry 7109226

Structure parameters

• Formula: C36 H54 Ge O4 Si3 W
• Calculated formula: C36 H54 Ge O4 Si3 W
• SMILES: [W]12345([Ge]([O]=C1c1ccccc1)(OCc1ccccc1)C([Si](C)(C)C)([Si](C)(C)C)[Si](C)(C)C)(C#[O])(C#[O])[c]1([c]2([c]3([c]4([c]51C)C)C)C)C
• Title of publication: Reactions of a tungsten-germylyne complex with alcohols and arylaldehydes
• Authors of publication: Tetsuya Fukuda; Hisako Hashimoto; Hiromi Tobita
• Journal of publication: Chem.Commun.
• Year of publication: 2013
• Journal volume: 49
• Pages of publication: 4232
• a: 8.9737 ± 0.0006 Å
• b: 25.6747 ± 0.0016 Å
• c: 16.6602 ± 0.001 Å
• α: 90°
• β: 100.478 ± 0.0014°
• γ: 90°
• Cell volume: 3774.5 ± 0.4 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0637
• Residual factor for significantly intense reflections: 0.0492
• Weighted residual factors for significantly intense reflections: 0.1157
• Weighted residual factors for all reflections included in the refinement: 0.1256
• Goodness-of-fit parameter for all reflections included in the refinement: 1.146
• Diffraction radiation wavelength: 0.71069 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No