Information card for entry 7109255

Structure parameters

• Formula: C46.5 H38 Cl N O3 P2 Ru
• Calculated formula: C46.5 H38 Cl N O3 P2 Ru
• Title of publication: Asymmetric cleavage of 2,2'-pyridil to a picolinic acid anion radical coordinated to ruthenium(II): splitting of water to hydrogen
• Authors of publication: Manas Kumar Biswas; Sarat Chandra Patra; Amarendra Nath Maity; Shyue-Chu Ke; Thomas Weyhermullerc; Prasanta Ghosh
• Journal of publication: Chem.Commun.
• Year of publication: 2013
• Journal volume: 49
• Pages of publication: 4522
• a: 11.123 ± 0.002 Å
• b: 11.397 ± 0.002 Å
• c: 18.288 ± 0.004 Å
• α: 89.57 ± 0.03°
• β: 75.48 ± 0.03°
• γ: 80.19 ± 0.03°
• Cell volume: 2210 ± 0.8 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1243
• Residual factor for significantly intense reflections: 0.0765
• Weighted residual factors for significantly intense reflections: 0.1941
• Weighted residual factors for all reflections included in the refinement: 0.2413
• Goodness-of-fit parameter for all reflections included in the refinement: 1.14
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No