Information card for entry 7110219

Structure parameters

• Formula: C37 H49 Ge N13
• Calculated formula: C37 H49 Ge N13
• SMILES: [Ge]1(=C2N(C=CN2CN2C=1N(C=C2)c1c(cccc1C(C)C)C(C)C)c1c(cccc1C(C)C)C(C)C)N=N#N.[N-]=N#N.N#CC.N#CC.N#CC
• Title of publication: Synthesis and structure of the azidogermyliumylidene azide complex [L(N3)Ge:]^+^N3^-^ with covalently and ionically bonded azide ligands at germanium(II) [L = bis(N-heterocyclic carbene)]
• Authors of publication: Yun Xiong; Shenglai Yao; Matthias Driess
• Journal of publication: Chem.Commun.
• Year of publication: 2014
• Journal volume: 50
• Pages of publication: 418
• a: 18.2975 ± 0.0012 Å
• b: 15.668 ± 0.0006 Å
• c: 15.2402 ± 0.0011 Å
• α: 90°
• β: 114.497 ± 0.009°
• γ: 90°
• Cell volume: 3975.8 ± 0.5 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 4
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.052
• Residual factor for significantly intense reflections: 0.0371
• Weighted residual factors for significantly intense reflections: 0.0761
• Weighted residual factors for all reflections included in the refinement: 0.0816
• Goodness-of-fit parameter for all reflections included in the refinement: 1.012
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No