Information card for entry 7110221

Structure parameters

• Formula: C57 H63 B Ge N8
• Calculated formula: C57 H63 B Ge N8
• Title of publication: Synthesis and structure of the azidogermyliumylidene azide complex [L(N3)Ge:]^+^N3^-^ with covalently and ionically bonded azide ligands at germanium(II) [L = bis(N-heterocyclic carbene)]
• Authors of publication: Yun Xiong; Shenglai Yao; Matthias Driess
• Journal of publication: Chem.Commun.
• Year of publication: 2014
• Journal volume: 50
• Pages of publication: 418
• a: 14.1299 ± 0.0003 Å
• b: 12.315 ± 0.0002 Å
• c: 30.9315 ± 0.0007 Å
• α: 90°
• β: 91.667 ± 0.002°
• γ: 90°
• Cell volume: 5380.1 ± 0.19 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0616
• Residual factor for significantly intense reflections: 0.0579
• Weighted residual factors for significantly intense reflections: 0.1469
• Weighted residual factors for all reflections included in the refinement: 0.1495
• Goodness-of-fit parameter for all reflections included in the refinement: 1.079
• Diffraction radiation wavelength: 1.5418 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No