Information card for entry 7110256

Structure parameters

• Formula: C22 H46 Ru Si2
• Calculated formula: C22 H46 Ru Si2
• SMILES: [RuH2]12345([Si](CC)(CC)CC)([Si](CC)(CC)CC)[cH]6[c]4([cH]3[cH]5[c]1([cH]26)C(C)C)C
• Title of publication: Ruthenium catalyzed selective hydrosilylation of aldehydes
• Authors of publication: Basujit Chatterjee; Chidambaram Gunanathan
• Journal of publication: Chem.Commun.
• Year of publication: 2014
• Journal volume: 50
• Pages of publication: 888
• a: 16.4631 ± 0.0015 Å
• b: 8.72 ± 0.0008 Å
• c: 17.7452 ± 0.0016 Å
• α: 90°
• β: 102.003 ± 0.004°
• γ: 90°
• Cell volume: 2491.8 ± 0.4 ų
• Cell temperature: 200 ± 2 K
• Ambient diffraction temperature: 200 ± 2 K
• Number of distinct elements: 4
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0359
• Residual factor for significantly intense reflections: 0.0299
• Weighted residual factors for significantly intense reflections: 0.071
• Weighted residual factors for all reflections included in the refinement: 0.0745
• Goodness-of-fit parameter for all reflections included in the refinement: 1.028
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No