Information card for entry 7110530

Structure parameters

• Formula: C11 H27 F6 N3 S Si
• Calculated formula: C11 H27 F6 N3 S Si
• Title of publication: Different fluoride anion sources and (trifluoromethyl)trimethylsilane: molecular structure of tris(dimethylamino)sulfonium bis(trifluoromethyl)trimethylsiliconate, the first isolated pentacoordinate silicon species with five Si‒C bonds
• Authors of publication: Kolomeitsev, Alexander; Movchun, Valery; Rusanov, Eduard; Bissky, German; Lork, Enno; Röschenthaler, Gerd-Volker; Kirsch, Peer
• Journal of publication: Chemical Communications
• Year of publication: 1999
• Journal issue: 11
• Pages of publication: 1017
• a: 7.698 ± 0.002 Å
• b: 11.321 ± 0.002 Å
• c: 11.356 ± 0.002 Å
• α: 90°
• β: 105.26 ± 0.01°
• γ: 90°
• Cell volume: 954.8 ± 0.3 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 6
• Space group number: 11
• Hermann-Mauguin space group symbol: P 1 21/m 1
• Hall space group symbol: -P 2yb
• Residual factor for all reflections: 0.0774
• Residual factor for significantly intense reflections: 0.0476
• Weighted residual factors for significantly intense reflections: 0.1002
• Weighted residual factors for all reflections included in the refinement: 0.1157
• Goodness-of-fit parameter for all reflections included in the refinement: 1.064
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No