Information card for entry 7110613

Structure parameters

• Formula: C104 H172 Si17
• Calculated formula: C104 H172 Si17
• SMILES: [Si](CC[Si](CC[Si](C=C)(C=C)C=C)(CC[Si](C=C)(C=C)C=C)CC[Si](C=C)(C=C)C=C)(CC[Si](CC[Si](C=C)(C=C)C=C)(CC[Si](C=C)(C=C)C=C)CC[Si](C=C)(C=C)C=C)(CC[Si](CC[Si](C=C)(C=C)C=C)(CC[Si](C=C)(C=C)C=C)CC[Si](C=C)(C=C)C=C)CC[Si](CC[Si](C=C)(C=C)C=C)(CC[Si](C=C)(C=C)C=C)CC[Si](C=C)(C=C)C=C
• Title of publication: Palladium complexes of phosphine functionalised carbosilane dendrimers as catalysts in a continuous flow membrane reactor†
• Authors of publication: de Groot, Debby; de Wilde, Janine C.; van Haaren, Richard J.; Reek, Joost N. H.; Kamer, Paul C. J.; van Leeuwen, Piet W. N. M.; Eggeling, Eva B.; Vogt, Dieter; Kooijman, Huub; Spek, Anthony L.; van der Made, Alexander W.
• Journal of publication: Chemical Communications
• Year of publication: 1999
• Journal issue: 17
• Pages of publication: 1623
• a: 17.297 ± 0.0004 Å
• b: 19.5782 ± 0.0004 Å
• c: 22.2298 ± 0.0005 Å
• α: 106.181 ± 0.0015°
• β: 108.143 ± 0.0015°
• γ: 106.674 ± 0.0014°
• Cell volume: 6268 ± 0.3 ų
• Cell temperature: 150 K
• Ambient diffraction temperature: 150 K
• Number of distinct elements: 3
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.2399
• Residual factor for significantly intense reflections: 0.136
• Weighted residual factors for significantly intense reflections: 0.244
• Weighted residual factors for all reflections included in the refinement: 0.2949
• Goodness-of-fit parameter for all reflections included in the refinement: 0.886
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No