Information card for entry 7111140

Structure parameters

• Formula: C16 H29 O4 P3 W
• Calculated formula: C16 H29 O4 P3 W
• SMILES: C(#[O])[W]1(C#[O])(C#[O])([P@@H](C(C)(C)C)P(C(C)(C)C)[P@H]1C(C)(C)C)C#[O]
• Title of publication: Electrophilic ring-opening of [(RP)nAs]− anions; a simple route to functionalised neutral phosphines of the type [(ButP)(ButRP)2]
• Authors of publication: Armstrong, David R.; Feeder, Neil; Hopkins, Alexander D.; Mays, Martin J.; Wood, Jody A.; Woods, Anthony D.; Wright, Dominic S.; Moncrieff, David
• Journal of publication: Chemical Communications
• Year of publication: 2000
• Journal issue: 24
• Pages of publication: 2483
• a: 17.3386 ± 0.0007 Å
• b: 13.7599 ± 0.0005 Å
• c: 9.461 ± 0.0004 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 2257.18 ± 0.16 ų
• Cell temperature: 180 ± 2 K
• Ambient diffraction temperature: 180 ± 2 K
• Number of distinct elements: 5
• Space group number: 62
• Hermann-Mauguin space group symbol: P n m a
• Hall space group symbol: -P 2ac 2n
• Residual factor for all reflections: 0.0436
• Residual factor for significantly intense reflections: 0.0267
• Weighted residual factors for all reflections: 0.0664
• Weighted residual factors for significantly intense reflections: 0.0616
• Goodness-of-fit parameter for all reflections: 1.076
• Goodness-of-fit parameter for significantly intense reflections: 1.108
• Diffraction radiation wavelength: 0.71069 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No