Information card for entry 7111575

Structure parameters

• Common name: (mu!2$-di-t-butylstanna)-tetracarbonyl-bis(eta$5!- cyclopentadienyl)-di-iron
• Chemical name: (μ~2~-di-t-butylstanna)-tetracarbonyl-bis(η^5^-cyclopentadienyl)-di-iron
• Formula: C22 H28 Fe2 O4 Sn
• Calculated formula: C22 H28 Fe2 O4 Sn
• SMILES: C(C)(C)([Sn](C(C)(C)C)([Fe]1234([cH]5[cH]1[cH]2[cH]3[cH]45)(C#[O])C#[O])[Fe]1234([cH]5[cH]1[cH]2[cH]3[cH]45)(C#[O])C#[O])C
• Title of publication: Methyl transfer from Fe (and Mo) to Sn: formation of (η5-C5H5)M(CO)nSntBu2Me (M = Fe, n = 2; M = Mo, n = 3) complexes from photochemical irradiation of (η5-C5H5)M(CO)nMe and tBu2SnH2
• Authors of publication: Sharma, Hemant K.; Arias-Ugarte, Renzo; Metta-Magana, Alejandro; Pannell, Keith H.
• Journal of publication: Chemical Communications
• Year of publication: 2010
• Journal volume: 46
• Journal issue: 25
• Pages of publication: 4586 - 4588
• a: 17.479 ± 0.005 Å
• b: 9.024 ± 0.002 Å
• c: 16.126 ± 0.004 Å
• α: 90°
• β: 113.611 ± 0.006°
• γ: 90°
• Cell volume: 2330.6 ± 1 ų
• Cell temperature: 298 ± 2 K
• Ambient diffraction temperature: 298 ± 2 K
• Number of distinct elements: 5
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0563
• Residual factor for significantly intense reflections: 0.0369
• Weighted residual factors for significantly intense reflections: 0.0756
• Weighted residual factors for all reflections included in the refinement: 0.0833
• Goodness-of-fit parameter for all reflections included in the refinement: 0.99
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No