Information card for entry 7111756

Structure parameters

• Common name: tetrakis(trimethylphosphine)rhodium(i) tetra(pentafluorophenyl)borate
• Chemical name: tetrakis(trimethylphosphine)rhodium(I) tetra(pentafluorophenyl)borate
• Formula: C36 H36 B F20 P4 Rh
• Calculated formula: C36 H36 B F20 P4 Rh
• SMILES: [Rh]([P](C)(C)C)([P](C)(C)C)([P](C)(C)C)[P](C)(C)C.Fc1c(F)c(F)c(F)c(F)c1[B-](c1c(F)c(F)c(F)c(F)c1F)(c1c(F)c(F)c(F)c(F)c1F)c1c(F)c(F)c(F)c(F)c1F
• Title of publication: Synthesis and structures of the homoleptic cations [M(PMe3)5]+ (M = Rh, Ir)
• Authors of publication: Rivers, Joseph H.; Jones, Richard A.
• Journal of publication: Chemical Communications
• Year of publication: 2010
• Journal volume: 46
• Journal issue: 24
• Pages of publication: 4300 - 4302
• a: 12.1222 ± 0.0009 Å
• b: 12.6241 ± 0.0009 Å
• c: 15.842 ± 0.0011 Å
• α: 104.712 ± 0.0017°
• β: 109.836 ± 0.0017°
• γ: 98.4962 ± 0.0018°
• Cell volume: 2131.6 ± 0.3 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0544
• Residual factor for significantly intense reflections: 0.045
• Weighted residual factors for significantly intense reflections: 0.102
• Weighted residual factors for all reflections included in the refinement: 0.1085
• Goodness-of-fit parameter for all reflections included in the refinement: 1.054
• Diffraction radiation wavelength: 0.71069 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No