Information card for entry 7111758

Structure parameters

• Common name: pentakis(trimethylphosphine)rhodium(i) bis(3,5- trifluoromethyl)pyrazolate
• Chemical name: pentakis(trimethylphosphine)rhodium(I) bis(3,5-trifluoromethyl)pyrazolate
• Formula: C20 H46 F6 N2 P5 Rh
• Calculated formula: C20 H46 F6 N2 P5 Rh
• Title of publication: Synthesis and structures of the homoleptic cations [M(PMe3)5]+ (M = Rh, Ir)
• Authors of publication: Rivers, Joseph H.; Jones, Richard A.
• Journal of publication: Chemical Communications
• Year of publication: 2010
• Journal volume: 46
• Journal issue: 24
• Pages of publication: 4300 - 4302
• a: 9.4967 ± 0.0011 Å
• b: 12.0818 ± 0.0014 Å
• c: 14.6363 ± 0.0017 Å
• α: 88.422 ± 0.004°
• β: 75.798 ± 0.003°
• γ: 77.305 ± 0.003°
• Cell volume: 1587.6 ± 0.3 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0309
• Residual factor for significantly intense reflections: 0.0294
• Weighted residual factors for significantly intense reflections: 0.0703
• Weighted residual factors for all reflections included in the refinement: 0.0714
• Goodness-of-fit parameter for all reflections included in the refinement: 0.974
• Diffraction radiation wavelength: 0.71069 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No