Information card for entry 7112031

Structure parameters

• Formula: C25 H35 Au F6 O P Sb
• Calculated formula: C25 H35 Au F6 O P Sb
• SMILES: [Au]([P](C(C)(C)C)(C(C)(C)C)c1ccccc1c1ccccc1)=C(C1CC1)OC.[Sb](F)(F)(F)(F)(F)[F-]
• Title of publication: Experimental evaluation of the electron donor ability of a gold phosphine fragment in a gold carbene complex
• Authors of publication: Rachel E. M. Brooner; Ross A. Widenhoefer
• Journal of publication: Chem.Commun.
• Year of publication: 2014
• Journal volume: 50
• Pages of publication: 2420
• a: 12.132 ± 0.005 Å
• b: 9.596 ± 0.004 Å
• c: 23.868 ± 0.007 Å
• α: 90°
• β: 91.292 ± 0.007°
• γ: 90°
• Cell volume: 2778 ± 1.8 ų
• Cell temperature: 110 K
• Ambient diffraction temperature: 110 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0746
• Residual factor for significantly intense reflections: 0.0424
• Weighted residual factors for significantly intense reflections: 0.0913
• Weighted residual factors for all reflections included in the refinement: 0.1026
• Goodness-of-fit parameter for all reflections included in the refinement: 1.04
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No