Information card for entry 7112083

Structure parameters

• Formula: C52 H90 As Li O8 P2
• Calculated formula: C52 H90 As Li O8 P2
• SMILES: [Li]123456([O]7CC[O]1CC[O]2CC[O]3CC7)[O]1CC[O]4CC[O]5CC[O]6CC1.[As+](=Pc1c(cc(cc1C(C)(C)C)C(C)(C)C)C(C)(C)C)=Pc1c(cc(cc1C(C)(C)C)C(C)(C)C)C(C)(C)C
• Title of publication: Direct access to [(Mes*P)2As]-, a 1,3-diphosphaarsa-2-allyl anion, isoelectronic with the allyl anion (Mes* = 2,4,6^-t^Bu3C6H2)
• Authors of publication: Lily S. H. Dixon; Lucy K. Allen; Robert J. Less; Dominic S. Wright
• Journal of publication: Chem.Commun.
• Year of publication: 2014
• Journal volume: 50
• Pages of publication: 3007
• a: 13.217 ± 0.001 Å
• b: 14.553 ± 0.002 Å
• c: 16.489 ± 0.002 Å
• α: 90.751 ± 0.003°
• β: 91.46 ± 0.003°
• γ: 115.777 ± 0.003°
• Cell volume: 2854.1 ± 0.6 ų
• Cell temperature: 180 ± 2 K
• Ambient diffraction temperature: 180 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1367
• Residual factor for significantly intense reflections: 0.1252
• Weighted residual factors for significantly intense reflections: 0.2521
• Weighted residual factors for all reflections included in the refinement: 0.2585
• Goodness-of-fit parameter for all reflections included in the refinement: 1.113
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No