Information card for entry 7112854

Structure parameters

• Formula: C31 H89 Li O Si12 Sn
• Calculated formula: C31 H89 Li O Si12 Sn
• SMILES: [Sn]([Si]([Si](C)(C)C)([Si](C)(C)C)[Si](C)(C)C)([Si]([Si](C)(C)C)([Si](C)(C)C)[Si](C)(C)C)([Si]([Si](C)(C)C)([Si](C)(C)C)[Si](C)(C)C)[Li][O]1CCCC1
• Title of publication: Sn[Si(SiMe3)3]3- and Sn3[Si(SiMe3)3]4: first insight into the mechanism of the disproportionation of a tin monohalide gives access to the shortest double bond of tin.
• Authors of publication: Schrenk, Claudio; Schnepf, Andreas
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2010
• Journal volume: 46
• Journal issue: 36
• Pages of publication: 6756 - 6758
• a: 12.937 ± 0.003 Å
• b: 23.193 ± 0.005 Å
• c: 18.878 ± 0.004 Å
• α: 90°
• β: 104.04 ± 0.03°
• γ: 90°
• Cell volume: 5495 ± 2 ų
• Cell temperature: 149 ± 2 K
• Ambient diffraction temperature: 149 ± 2 K
• Number of distinct elements: 6
• Space group number: 9
• Hermann-Mauguin space group symbol: C 1 c 1
• Hall space group symbol: C -2yc
• Residual factor for all reflections: 0.0314
• Residual factor for significantly intense reflections: 0.0299
• Weighted residual factors for significantly intense reflections: 0.0753
• Weighted residual factors for all reflections included in the refinement: 0.076
• Goodness-of-fit parameter for all reflections included in the refinement: 1.023
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No