Information card for entry 7113184

Structure parameters

• Common name: Ti(MeN(CH2CH2SiMe3)2)(NNNPh2)(py)
• Chemical name: Ti{MeN(CH2CH2SiMe3)2}(NNNPh2)(py)
• Formula: C28 H44 N6 Si2 Ti
• Calculated formula: C28 H44 N6 Si2 Ti
• Title of publication: New ligand platforms for developing the chemistry of the Ti=N‒NR2 functional group and the insertion of alkynes into the N‒N bond of a Ti=N‒NPh2 ligand
• Authors of publication: Selby, Jonathan D.; Manley, Catherine D.; Feliz, Marta; Schwarz, Andrew D.; Clot, Eric; Mountford, Philip
• Journal of publication: Chemical Communications (Cambridge, United Kingdom)
• Year of publication: 2007
• Journal issue: 46
• Pages of publication: 4937 - 4939
• a: 10.1794 ± 0.0005 Å
• b: 11.18 ± 0.0007 Å
• c: 13.8952 ± 0.0008 Å
• α: 89.726 ± 0.003°
• β: 77.178 ± 0.002°
• γ: 85.912 ± 0.003°
• Cell volume: 1537.9 ± 0.15 ų
• Cell temperature: 150 K
• Ambient diffraction temperature: 150 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1286
• Residual factor for significantly intense reflections: 0.0728
• Weighted residual factors for all reflections: 0.1097
• Weighted residual factors for significantly intense reflections: 0.08
• Weighted residual factors for all reflections included in the refinement: 0.08
• Goodness-of-fit parameter for all reflections included in the refinement: 1.2067
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Duplicate of: 7102305
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No