Information card for entry 7114132

Structure parameters

• Formula: C8 H24 F6 O4 P Rh S4
• Calculated formula: C8 H24 F6 O4 P Rh S4
• SMILES: [Rh]([O]=S(C)C)([S](=O)(C)C)([S](=O)(C)C)[O]=S(C)C.[P](F)(F)(F)(F)(F)[F-]
• Title of publication: The first fully characterized neutral and cationic rhodium(i)-complexes containing DMSO as the only dative ligand; S-, O- and bridging S,O-bidentate binding modes
• Authors of publication: Dorta, Reto; Rozenberg, Haim; Milstein, David
• Journal of publication: Chemical Communications
• Year of publication: 2002
• Journal issue: 7
• Pages of publication: 710
• a: 8.858 ± 0.0018 Å
• b: 5.993 ± 0.0012 Å
• c: 19.061 ± 0.004 Å
• α: 90°
• β: 92.5 ± 0.03°
• γ: 90°
• Cell volume: 1010.9 ± 0.4 ų
• Cell temperature: 120 ± 2 K
• Ambient diffraction temperature: 120 ± 2 K
• Number of distinct elements: 7
• Space group number: 7
• Hermann-Mauguin space group symbol: P 1 c 1
• Hall space group symbol: P -2yc
• Residual factor for all reflections: 0.028
• Residual factor for significantly intense reflections: 0.0262
• Weighted residual factors for significantly intense reflections: 0.064
• Weighted residual factors for all reflections included in the refinement: 0.065
• Goodness-of-fit parameter for all reflections included in the refinement: 1.03
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No