Information card for entry 7114346

Structure parameters

• Formula: C45 H21 Eu2 F36 N3 O15
• Calculated formula: C45 H21 Eu2 F36 N3 O15
• SMILES: [Eu]12345([O]=C(C(F)(F)F)C=C(O1)C(F)(F)F)([O](=n1ccccc1)[Eu]167([O]=C(C(F)(F)F)C=C(O1)C(F)(F)F)([O]=C(C(F)(F)F)C=C(O7)C(F)(F)F)(OC(=CC(=[O]6)C(F)(F)F)C(F)(F)F)([O]4=n1ccccc1)[O]5=n1ccccc1)([O]=C(C(F)(F)F)C=C(O2)C(F)(F)F)[O]=C(C(F)(F)F)C=C(O3)C(F)(F)F
• Title of publication: The first perfluoroacetylacetonate metal complexes: as unexpectedly robust as tricky to makeElectronic supplementary information (ESI) available: details of the preparation of the complexes, analytical, NMR spectroscopical, and crystallographic data. See: http://www.rsc.org/suppdata/cc/b1/b111249j/
• Authors of publication: Petrov, Viacheslav A.; Marshall, William J.; Grushin, Vladimir V.
• Journal of publication: Chemical Communications
• Year of publication: 2002
• Journal issue: 5
• Pages of publication: 520
• a: 19.58 ± 0.004 Å
• b: 14.668 ± 0.003 Å
• c: 21.29 ± 0.005 Å
• α: 90 ± 0.01°
• β: 93.527 ± 0.01°
• γ: 90 ± 0.01°
• Cell volume: 6103 ± 2 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0774
• Residual factor for significantly intense reflections: 0.0438
• Weighted residual factors for significantly intense reflections: 0.1049
• Weighted residual factors for all reflections included in the refinement: 0.1192
• Goodness-of-fit parameter for all reflections included in the refinement: 0.986
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No