Information card for entry 7114566

Structure parameters

• Formula: C45 H57 Ge3 P3 Pt3
• Calculated formula: C45 H57 Ge3 P3 Pt3
• SMILES: [Pt]123([Pt]4([Pt]1([Ge]4(c1ccccc1)c1ccccc1)([Ge]2(c1ccccc1)c1ccccc1)[P](C)(C)C)([Ge]3(c1ccccc1)c1ccccc1)[P](C)(C)C)[P](C)(C)C
• Title of publication: A triangular triplatinum(0) complex with bridging germylene ligands: insertion of alkynes into the Pt‒Ge bond rather than the Pt‒Pt bond
• Authors of publication: Tanabe, Makoto; Tanaka, Kimiya; Omine, Shumpei; Osakada, Kohtaro
• Journal of publication: Chemical Communications (Cambridge, United Kingdom)
• Year of publication: 2014
• Journal volume: 50
• Journal issue: 52
• Pages of publication: 6839 - 6842
• a: 12.539 ± 0.002 Å
• b: 13.863 ± 0.002 Å
• c: 15.866 ± 0.003 Å
• α: 66.82 ± 0.008°
• β: 79.268 ± 0.01°
• γ: 66.814 ± 0.009°
• Cell volume: 2328.9 ± 0.7 ų
• Cell temperature: 293 K
• Ambient diffraction temperature: 293 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for significantly intense reflections: 0.031
• Weighted residual factors for all reflections included in the refinement: 0.0925
• Goodness-of-fit parameter for all reflections included in the refinement: 1.026
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No