Information card for entry 7114568

Structure parameters

• Formula: C53 H65 Ge3 O4 P3 Pt3
• Calculated formula: C53 H65 Ge3 O4 P3 Pt3
• SMILES: [Pt]1234([Pt]56([Pt]71([Ge]([C]3(C(=O)OC)=[CH]4[Ge]5(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)([P](C)(C)C)[C]6(C(=O)OC)=[CH]7[Ge]2(c1ccccc1)c1ccccc1)[P](C)(C)C)[P](C)(C)C
• Title of publication: A triangular triplatinum(0) complex with bridging germylene ligands: insertion of alkynes into the Pt‒Ge bond rather than the Pt‒Pt bond
• Authors of publication: Tanabe, Makoto; Tanaka, Kimiya; Omine, Shumpei; Osakada, Kohtaro
• Journal of publication: Chemical Communications (Cambridge, United Kingdom)
• Year of publication: 2014
• Journal volume: 50
• Journal issue: 52
• Pages of publication: 6839 - 6842
• a: 21.046 ± 0.006 Å
• b: 12.804 ± 0.004 Å
• c: 20.027 ± 0.005 Å
• α: 90°
• β: 93.534 ± 0.003°
• γ: 90°
• Cell volume: 5386 ± 3 ų
• Cell temperature: 90 ± 2 K
• Ambient diffraction temperature: 90 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.106
• Residual factor for significantly intense reflections: 0.0921
• Weighted residual factors for significantly intense reflections: 0.2482
• Weighted residual factors for all reflections included in the refinement: 0.2617
• Goodness-of-fit parameter for all reflections included in the refinement: 0.981
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No