Information card for entry 7115079

Structure parameters

• Formula: C56 H47 Mo O4 P3 Pt2
• Calculated formula: C56 H45 Mo O4 P3 Pt2
• Title of publication: Unexpected bonding similarities between the bridging metalloligands [MoCp(CO)3]− and [PtI(CO)2(PPh3)]− acting as 4-electron donors in metal clusters. Crystal structures of [Pt2Mo(μ-CO)3(μ-PPh2)Cp(PPh3)2] and [Pt3(μ-CO)2(μ-PPh2)I(PPh3)3]
• Authors of publication: Archambault, Christine; Bender, Robert; Braunstein, Pierre; Bouaoud, Salah-Eddine; Rouag, Djemel; Golhen, Stéphane; Ouahab, Lahcène
• Journal of publication: Chemical Communications
• Year of publication: 2001
• Journal issue: 9
• Pages of publication: 849
• a: 12.053 ± 0.001 Å
• b: 13.69 ± 0.001 Å
• c: 17.292 ± 0.003 Å
• α: 109.271 ± 0.006°
• β: 92.541 ± 0.006°
• γ: 106.169 ± 0.006°
• Cell volume: 2557.5 ± 0.5 ų
• Cell temperature: 173 K
• Ambient diffraction temperature: 173 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.042
• Residual factor for significantly intense reflections: 0.023
• Weighted residual factors for all reflections: 0.566
• Weighted residual factors for all reflections included in the refinement: 0.034
• Goodness-of-fit parameter for all reflections: 18.454
• Goodness-of-fit parameter for all reflections included in the refinement: 1.095
• Diffraction radiation wavelength: 0.7093 Å
• Diffraction radiation type: Mo-Kα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No