Structural isomers of M(dca)2 molecule-based magnets. Crystal structure of tetrahedrally coordinated sheet-like β-Zn(dca)2 and β-Co/Zn(dca)2, and the octahedrally coordinated rutile-like α-Co(dca)2, where dca‒ = dicyanamide, N(CN)2−, and magnetism of β-Co(dca)2
Authors of publication
Jensen, Paul; Batten, Stuart R.; Fallon, Gary D.; Moubaraki, Boujemaa; Murray, Keith S.; Price, David J.
Journal of publication
Chemical Communications
Year of publication
1999
Journal issue
2
Pages of publication
177
a
7.607 ± 0.0003 Å
b
7.5828 ± 0.0004 Å
c
11.8468 ± 0.0006 Å
α
90°
β
90°
γ
90°
Cell volume
683.35 ± 0.06 Å3
Cell temperature
123.2 K
Ambient diffraction temperature
123.2 K
Number of distinct elements
3
Space group number
62
Hermann-Mauguin space group symbol
P n m a
Hall space group symbol
-P 2ac 2n
Residual factor for significantly intense reflections
0.0273
Weighted residual factors for significantly intense reflections
0.0244
Goodness-of-fit parameter for significantly intense reflections
