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Information card for entry 7115607
Preview
Coordinates | 7115607.cif |
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Original paper (by DOI) | HTML |
Formula | C21 H26 N6 O2 Si |
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Calculated formula | C21 H26 N6 O2 Si |
SMILES | [Si](OC([C@@]1(OCCC[C@@H]1N=N#N)N=N#N)(c1ccccc1)c1ccccc1)(C)(C)C.[Si](OC([C@]1(OCCC[C@H]1N=N#N)N=N#N)(c1ccccc1)c1ccccc1)(C)(C)C |
Title of publication | A Mn(III)/TEMPO-co-mediated tandem azidation-1,2-carbon migration reaction of allylic silyl ethers |
Authors of publication | Zhi-Min Chen; Zhen Zhang; Yong-Qiang Tu; Ming-Hui Xu; Fu-Min Zhang; Chen-Chen Li; Shao-Hua Wang |
Journal of publication | Chem.Commun. |
Year of publication | 2014 |
Journal volume | 50 |
Pages of publication | 10805 |
a | 8.7189 ± 0.0003 Å |
b | 9.066 ± 0.0004 Å |
c | 27.8157 ± 0.0013 Å |
α | 90° |
β | 91.003 ± 0.004° |
γ | 90° |
Cell volume | 2198.37 ± 0.16 Å3 |
Cell temperature | 293 ± 2 K |
Ambient diffraction temperature | 293 ± 2 K |
Number of distinct elements | 5 |
Space group number | 14 |
Hermann-Mauguin space group symbol | P 1 21/c 1 |
Hall space group symbol | -P 2ybc |
Residual factor for all reflections | 0.0912 |
Residual factor for significantly intense reflections | 0.0545 |
Weighted residual factors for significantly intense reflections | 0.1121 |
Weighted residual factors for all reflections included in the refinement | 0.1314 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.036 |
Diffraction radiation wavelength | 0.71073 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
For the version history of this entry, please navigate to main COD server.
The link is: https://www.crystallography.net/7115607.html
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