Information card for entry 7115988

Structure parameters

• Formula: C41 H54 Al Cl P Rh
• Calculated formula: C41 H54 Al Cl P Rh
• SMILES: C(C)(C)(C)[Al]1(C(C)(C)C)C(=C\c2ccccc2)/[P](c2c(cc(cc2C)C)C)(c2c(cc(cc2C)C)C)[Rh]234([CH]5=[CH]2C2CC5[CH]3=[CH]42)[Cl]1
• Title of publication: Novel zwitterionic complexes arising from the coordination of an ambiphilic phosphorus-aluminum ligand to gold
• Authors of publication: Marc Devillard; Emmanuel Nicolas; Christian Appelt; Jana Backs; Sonia Mallet-Ladeira; Ghenwa; Bouhadir'; J. Chris Slootweg; Werner Uhl; Didier Bourissou
• Journal of publication: Chem.Commun.
• Year of publication: 2014
• Journal volume: 50
• Pages of publication: 14805
• a: 11.5935 ± 0.0014 Å
• b: 12.8808 ± 0.0017 Å
• c: 14.3137 ± 0.0018 Å
• α: 80.717 ± 0.006°
• β: 72.804 ± 0.005°
• γ: 68.413 ± 0.005°
• Cell volume: 1895.4 ± 0.4 ų
• Cell temperature: 193 ± 2 K
• Ambient diffraction temperature: 193 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0537
• Residual factor for significantly intense reflections: 0.0353
• Weighted residual factors for significantly intense reflections: 0.0682
• Weighted residual factors for all reflections included in the refinement: 0.0754
• Goodness-of-fit parameter for all reflections included in the refinement: 1.039
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No