Information card for entry 7116159

Structure parameters

• Chemical name: bis(bis(triisopropylsilyl)amido) samarium
• Formula: C36 H84 N2 Si4 Sm
• Calculated formula: C36 H84 N2 Si4 Sm
• SMILES: C(C)(C)[Si](C(C)C)(C(C)C)N([Si](C(C)C)(C(C)C)C(C)C)[Sm]N([Si](C(C)C)(C(C)C)C(C)C)[Si](C(C)C)(C(C)C)C(C)C
• Title of publication: The first near-linear bis(amide) f-block complex: a blueprint for a high temperature single molecule magnet
• Authors of publication: Nicholas F. Chilton; Conrad A. P. Goodwin; David P. Mills; Richard E. P. Winpenny
• Journal of publication: Chem.Commun.
• Year of publication: 2015
• Journal volume: 51
• Pages of publication: 101
• a: 20.509 ± 0.002 Å
• b: 16.0788 ± 0.0019 Å
• c: 26.515 ± 0.002 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 8743.6 ± 1.5 ų
• Cell temperature: 150.03 ± 0.12 K
• Ambient diffraction temperature: 150.03 ± 0.12 K
• Number of distinct elements: 5
• Space group number: 61
• Hermann-Mauguin space group symbol: P b c a
• Hall space group symbol: -P 2ac 2ab
• Residual factor for all reflections: 0.1959
• Residual factor for significantly intense reflections: 0.0728
• Weighted residual factors for significantly intense reflections: 0.0797
• Weighted residual factors for all reflections included in the refinement: 0.1085
• Goodness-of-fit parameter for all reflections included in the refinement: 0.977
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No