Information card for entry 7116710

Structure parameters

• Common name: [PdCl2(BAC)]2
• Chemical name: dichloro-[bis(diisopropylamino)cyclopropenylidene] palladium dimer
• Formula: C30.5 H57 Cl5 N4 Pd2
• Calculated formula: C30.5 H57 Cl5 N4 Pd2
• Title of publication: A simple access to transition metal cyclopropenylidene complexes
• Authors of publication: Yannick D. Bidal; Mathieu Lesieur; Mohand Melaimi; David B. Cordes; Alexandra M. Z. Slawin; Guy Bertrand; Catherine S. J. Cazin
• Journal of publication: Chem.Commun.
• Year of publication: 2015
• Journal volume: 51
• Pages of publication: 4778
• a: 8.6743 ± 0.001 Å
• b: 15.139 ± 0.0018 Å
• c: 15.947 ± 0.002 Å
• α: 86.794 ± 0.007°
• β: 85.946 ± 0.007°
• γ: 80.765 ± 0.006°
• Cell volume: 2059.7 ± 0.4 ų
• Cell temperature: 173 K
• Ambient diffraction temperature: 173 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0645
• Residual factor for significantly intense reflections: 0.0444
• Weighted residual factors for significantly intense reflections: 0.113
• Weighted residual factors for all reflections included in the refinement: 0.1218
• Goodness-of-fit parameter for all reflections included in the refinement: 1.008
• Diffraction radiation wavelength: 0.71075 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No