Information card for entry 7117409

Structure parameters

• Formula: C52 H82 N4 O10 P2 Si6 W2
• Calculated formula: C52 H82 N4 O10 P2 Si6 W2
• Title of publication: Facile rotation around a silicon-phosphorus double bond enabled through coordination to tungsten
• Authors of publication: Nora C. Breit; Tibor Szilvasi; Shigeyoshi Inoue
• Journal of publication: Chem.Commun.
• Year of publication: 2015
• Journal volume: 51
• Pages of publication: 11272
• a: 18.8405 ± 0.0003 Å
• b: 10.1491 ± 0.0002 Å
• c: 34.9207 ± 0.0005 Å
• α: 90°
• β: 92.318 ± 0.001°
• γ: 90°
• Cell volume: 6671.87 ± 0.19 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 7
• Space group number: 15
• Hermann-Mauguin space group symbol: I 1 2/a 1
• Hall space group symbol: -I 2ya
• Residual factor for all reflections: 0.0397
• Residual factor for significantly intense reflections: 0.0361
• Weighted residual factors for significantly intense reflections: 0.0854
• Weighted residual factors for all reflections included in the refinement: 0.0881
• Goodness-of-fit parameter for all reflections included in the refinement: 1.066
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No