Information card for entry 7117816

Structure parameters

• Chemical name: 2xHOBpin
• Formula: C25 H55 B2 O7 P2 Rh
• Calculated formula: C25 H55 B2 O7 P2 Rh
• Title of publication: Remarkable reactivity of a rhodium(I) boryl complex towards CO2 and CS2: isolation of a carbido complex
• Authors of publication: Sabrina I. Kallane; Thomas Braun; Michael Teltewskoi; Beatrice Braun; Roy Herrmann; Reik Laubenstein
• Journal of publication: Chem.Commun.
• Year of publication: 2015
• Journal volume: 51
• Pages of publication: 14613
• a: 10.9348 ± 0.0007 Å
• b: 25.1626 ± 0.0017 Å
• c: 12.1658 ± 0.0008 Å
• α: 90°
• β: 93.209 ± 0.002°
• γ: 90°
• Cell volume: 3342.1 ± 0.4 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0243
• Residual factor for significantly intense reflections: 0.0232
• Weighted residual factors for significantly intense reflections: 0.0597
• Weighted residual factors for all reflections included in the refinement: 0.0606
• Goodness-of-fit parameter for all reflections included in the refinement: 1.052
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No